The invention provides compositions, methods and devices relating to a silaceous oxide that generates a reduced heat of hydration upon contact with blood. The system reads outputs of an oxygen sensor and an ammonia sensor that are installed in downstream of an NSR catalyst when the catalyst is in an activate condition. System-created events, such as recurring, minimum charge summary, and maximum charge summary events, are created by the system based on a schedule defined by a subscription to which a customer has subscribed. Pressure is provided by the static pressure plenum against the precursor web and the forming structure to conform the precursor web to the discrete protruded elements of the forming structure to form the embossed web.