An improved fishing or hunting wader, exposure suit or foul weather pantsbib incorporates a novel waterproof connectable hatch to provide access for urination. The latex can become a film, sheet, or other article. The invention allows the linking of audience profile information, such as demographic characteristics to audience behavior and content preferences. The macro-branched polymers exhibit desirable properties, such as an extremely high molecular weight, a controlled molecular weight distribution, Tg and vinyl content, and the ability to readily absorb hydrocarbon solvents and oils.