Methods for synthesizing extra low-k CVD precursors and forming extra low-k dielectric films on the surfaces of semiconductors wafers and integrated circuits are disclosed. In particular, compounds described herein are useful for treating or preventing diseases, conditions andor disorders modulated by TRPA1. The first and second apertures are configured to receive a tapered end of an expansion rod having an annular groove proximate the tapered end. The tibial mold may further comprise a sidewall forming a cavity, markings for relative depth measurement, and depth rings for use as a guide for scoring, cutting, andor trimming and tearing away an excess portion of the tibial mold.