A novel crystalline hybrid solid with a mixed organic-inorganic matrix is described which has a three-dimensional structure containing an inorganic framework with metallic centers based on zinc connected together via deprotonated organic ligands constituted by the entity \u2014O2C\u2014C6H2\u20142\u2014CO2. The tellurite glass composite includes an entire composite including 25 \u2266TeO2\u226690, 1 \u2266T1O3\u226655 or 1 \u2266T2O3\u226640, 0 \u2266ZnO\u226635, 0 \u2266M2O\u226635, and 0 \u2266Bi2O3\u226620. Sealant is positioned within the overlapping joints of the panels.