Briefly, a novel material process is disclosed wherein one or more nucleation modifiers are added, in trace amounts, to a lead-free tin-rich solder alloy to produce a solder composition with reduce or suppressed undercooling temperature characteristics. The compounds of this invention are novel therapeutic agents for the treatment of cancer, metabolic diseases and skin disorders in mammalian subjects. The wrist provides dexterity so that the end effector can be placed on the heart to stabilize the same. In response to a determination that the at least one developer has made a change to the portion of interest, a notification may be produced about the change to the portion of interest by the at least one developer. The controller modulates the light channels such that each of the 5 frames has different lighting characteristics.