A method for analyzing a structure of a substance of interest uses triple-quadrupole mass spectrometry, and allows for acquisition of MSn information from data resulting from the TQ-MS measurement. In the method, a binding range is selected from a plurality of binding ranges of content use based on license information of the content, and the content is encrypted based on the selected binding range so that the content can be used only within the selected binding range. The annunciator has an engine communication interface for communicating with the controller, a display, interface electronics for causing the display to indicate status reported by the engine controller a network interface, and a computer processor coupled to the interface electronics, the engine communication interface and the network interface.